Preliminary Metallurgical Investigation of Copper-Based Artifacts at Tepe Sagzabad in Qazvin Plain, Iran (1500-800 BC)

Document Type : Research Article

Authors

1 Faculty of Conservation, Art University of Isfahan, Isfahan, Iran

2 Department of Materials Engineering, Isfahan University of Technology, Isfahan, Iran

3 Department of Archaeology, University of Tehran, Tehran, Iran

Abstract

Tepe Sagzabad, a site situated on the Qazvin Plain of north-central Iran, was excavated from 1970 to 1998 by the Institute of
Archaeology of Tehran University. Recent excavations by H. Tala’i (1997-1999) yielded some metal artifacts dating to the
Early Iron Age. Ten of these copper-based samples were investigated using inductively coupled plasma optical emission
spectroscopy (ICP-OES), scanning electron microscopy combined with energy dispersive X-ray spectroscopy (SEMEDX)
and optical microscopy (OM). The results of these analyses showed that the metal objects at Tepe Sagzabad are
made of different copper alloys, including: pure copper, copper-arsenic and copper-tin. In addition, multiple procedures,
including hot-working, cold-working, and annealing were used as manufacturing techniques. The copper-based objects
from Tepe Sagzabad provide evidence for the continued use of pure copper and arsenical copper alongside tin bronzes on
the Iranian Plateau during the Early Iron Age.

Keywords


Artioli, Gilberto.2010 Scientific Methods and Cultural Heritage:An introduction to the application
of materials science to archaeometryand conservation science. UK: OxfordUniversity Press.
Begemann, Friedrich; Ernie Haerinck; Bruno Overleat;Sigrid Schmitt-Strecker & Françoise Tallon.
2008 An archaeo-metallurgical study of the earlyand middle bronze age in Luristan, Iran.Iranica Antiqua XLIII:1-66.
Chiavari, Cristina; Michele Degli Esposti; Gian Luca
Garagnani & Carla Martini.
2011 Ancient Metallurgy at the Sumhuram(Sultanate of Oman): Technical Aspects ofRaised Inscriptions on South Arabian
Bronze. Archaeometry 53 (3): 528-546.
Coghlan, Herbert Henery.1975 Note on the prehistoric Metallurgy ofCopper and Bronze in the Old World. UK:
Oxford University Press.
Eaton. Ethel R & Hugh Mckerrell.1976 Near Eastern Alloying and Some TextualEvidence for the Early Use of Arsenical
Copper. World Archaeology 8(2): 169-191.Climatic Change
.Fleming, Stuart J; Vincent C. Pigott; Charles P. Swann& Samuel K. Nash.2005 Bronze in Luristan: Preliminary Analytical
Evidence from Copper / Bronze ArtifactsExcavated by the Belgian Mission in Iran.
Iranica Antiqua XL: 35-64.
Fleming, Stuart J; Vincent C. Pigott; Charles P. Swann;Samuel K. Nash; Ernie Haerinck & Bruno Overleat.2006 The Archaeometallurgy of War Kabud,Western Iran. Iranica Antiqua XLI: 31-56.
Frame, Lesley.2010 Metallurgical Investigations at Godin Tepe,Iran, Part I: The Metal Finds. Journal ofArchaeological Science 37: 1700-1715.
Junk, Margrit.2003 Material Properties of Copper AlloysContaining Arsenic, Antimony, and
Bismuth, the Material of Early BronzeAge ingot torques. Unpublished Ph.DDissertation, der Technischen Universität
Bergakademie Freiberg.
Lechtman, Heather.1996 Arsenic Bronze: Dirty Copper or ChosenAlloy? A View from the Americas. Journalof Field Archaeology 23(4): 477-514.
Lechtman, Heather & Sabine Klein.1999 The Production of copper – Arsenic Alloys(Arsenic Bronze) by cosmelting, Modern
Experiment, Ancient Practice. Journal of
Archaeological Science 26:497-526.
Malek Shahmirzadi, Sadegh.1979 Copper, Bronze and their Implementationby Metalsmiths of Sagzabad Qazvin Plain,
Iran. AMI 12: 49-66.
Moorey, Peter R.S.1969 Prihistoric Copper and Bronze Metallurgy inWestern Iran, with Special reference to
Luristan. Iran XVII:131-154.
Negahban, Ezatollah.1976 Preliminary Report of the Excavation ofSagzabad . The Memorial Volume of theVIth International Congress of Iranian Art& Archaeology, September 11-16th 1972:247-271. Tehran: Publication of the Iranian
Centre for Archaeological Research.
Nezafati, Nima; Ernst Pernicka & Sadegh MalekShahmirzadi.2008 Evidence on the Ancient Mining and
Metallurgy at Tappeh Sialk (Central Iran).
In Ṻ. Yalcin; H. Özbal & A. G.Paşamehmetoglu (eds.) Ancient Miningin Turkey and the Eastern Mediterranean:329-349. Ankara: Atilim University.Park, Jang Sik; Cheol Woo Park & Keun June Lee.
2009 Implication of Peritectic Composition inHistorical High - tin Bronze Metallurgy.Materials Characterization 60: 1268-1275.
Pigott, Vincent C.2004a On the Importance of Iran in the Study ofPrehistoric Copper - base Metallurgy. InT.Stöllner; R. Slotta & A. Vatandoust (eds.)Persia’s Ancient Splendour, Mining,Handicraft and Archaeology: 28 - 43.Bochum: Deutsches Bergbau-Museum.
2004b Hasanlu and the Emergence of Iran inEarly 1st Millennium BC Western Iran. InT. Stöllner; R.Slotta & A. Vatandoust(eds. )Persia’s Ancient Splendour, Mining,Handicraft and Archaeology: 350-357.Bochum: Deutsches Bergbau-Museum.
1999 The Development of Metal Production on
the Iranian Plateau;an ArchaeometallurgicalPerspective. In V. C. Pigott (ed.) TheArchaeometallurgy of The Asian old world:73 - 106. Philadelphia : Unversity ofPennysylvania Museum Press.
Roustaei, Kourosh.2004 A Major Manufacturing Centre at theCentral Plateau. In T. Stöllner, R. Slotta &A. Vatandoust (eds.) Persia’s AncientSplendour, Mining, Handicraft andArchaeology: 222-230. Bochum: DeutschesBergbau- Museum,
Scott, David A.1991 Metallography and Microstructure ofAncient and Historic Metals. Los Angeles:Getty Conservation institute.
Tala’i, Hassan.2002 Ancient Metalworking in Tepe Sagzabad.Journal of Faculty of Letters and
Humanities ( In Persian ) 164: 547 - 564.Tehran University.
1984 Notes on Bronze Artifacts at Sagzabad inQazvin Plain, Iran, Circa 1400 B.C. IranicaAntiqua XIX: 31-42.
1983 Late Bronze Age and Iron Age IArchitecture in Sagzabad-Qazvin Plain-TheCentral Plateau of Iran. Iranica AntiquaXVIII: 51-57.
Thornton, Christopher P; Carl C. Lamberg-Karlovsky;Martin Liezers & Suzanne M. M. Young.2002 On Pins and Needle: Tracing the Evolutionof Copper-base Alloying at TepeYahya, Iran,via ICP - MS analysis of common - placeitems. Journal of Archaeological Science29: 1451-1460.
Thornton, Christopher P &Carl C. Lamberg-Karlovsky.2004 Tappeh Yahya and the PrehistoricMetallorgy of South - eastern Iran. In T.Stöllner; R. Slotta & A. Vatandoust (eds.)Persia’s Ancient Splendour, Mining,Handicraft and Archaeology: 264-273.Bochum: Deutsches Bergbau-Museum.
Thornton, Christopher P.2009 The Emergence of Complex Metallurgy onthe Iranian Plateau: Escaping the LevantineParadigm. Journal of World Prehistory 22:301-327.